A Neuro-Fuzzy Algorithm for Modeling of Fischer-Tropsch Synthesis over a Bimetallic Co/Ni/Al2O3 Catalyst

Authors

Abstract:

An alumina supported Co/Ni catalyst was prepared by sol-gel procedure to study the catalytic behavior during Fischer-Tropsch synthesis in a fixed-bed reactor. The effect of CO conversion (10-50%) on hydrocarbon product distribution (CH4, C5+ and C2-C4 olefin selectivities) was studied. Selectivity for CH4 decreased, while those of C5+ and olefin selectivities increased with increasing CO conversion. The catalysts properties were characterized at different stages using powder X-Ray Diffraction (XRD), Brunauer-Emmett-Teller (BET) surface area measurements, and Scanning electron microscopy (SEM). A neuro-fuzzy model called locally liner model tree (LoLiMoT) was applied to predict the catalytic behavior during Fischer-Tropsch reaction over the Co/Ni/Al2O3 catalyst. The predicting system was established on CO conversion values as a target based on three variables, including partial pressure of CO and H2, and H2/CO feed ratios as the input. To evaluate the generalization performance of the system, the k-fold cross validation was applied so that an excellent prediction was observed with mean square error (MSE) which equals 7.4211e-004. Finally, the extrapolation ability of LoLiMoT was perused (beyond the training range). The obtained data from LoLiMoT were compared with the experimental data, and the results indicated that LoLiMoT is a worthy system modeling with high capability for data prediction, both within and beyond the training range.

Upgrade to premium to download articles

Sign up to access the full text

Already have an account?login

similar resources

a neuro-fuzzy algorithm for modeling of fischer-tropsch synthesis over a bimetallic co/ni/al2o3 catalyst

an alumina supported co/ni catalyst was prepared by sol-gel procedure to study the catalytic behavior during fischer-tropsch synthesis in a fixed-bed reactor. the effect of co conversion (10-50%) on hydrocarbon product distribution (ch4, c5+ and c2-c4 olefin selectivities) was studied. selectivity for ch4 decreased, while those of c5+ and olefin selectivities increased with increasing co conver...

full text

Aqueous-phase Fischer-Tropsch synthesis with a ruthenium nanocluster catalyst.

Introduction Hydrogenation of carbon monoxide to produce hydrocarbons, normally called Fischer-Tropsch synthesis (F-T synthesis), is one of the most important hydrogenation reactions due to its potential for the intermediate production of hydrocarbon fuels in the “postpetroleum” era. The reaction is favored at low-temperature and therefore reducing the particle size of the catalyst to several n...

full text

Fischer–Tropsch synthesis on a model Co/SiO2 catalyst

A model Co/SiO2 catalyst was prepared by depositing cobalt on silica films in ultrahigh vacuum conditions. Fischer–Tropsch synthesis was carried out at a total pressure of carbon monoxide and hydrogen between 0.33 and 1.0 bar. The effects of reaction temperature and pressure on kinetics and chain growth probability were investigated. The turnover frequency, activation energy, and product distri...

full text

Fischer-Tropsch Synthesis on Bimetallic Ruthenium-Gold Catalysts

The effect of Au in the behavior of Ru as a Fischer-Tropsch catalyst was studied. Two series of catalysts were investigated, one supported on Si02 and the other on MgO. Au did not seem to alter the product distribution on Ru at pressures up to 1 MPa and in the temperature range 490-570 K. However, the turnover frequencies for both CO hydrogenation and methanation showed a precipitous drop with ...

full text

Mathematical modeling of a fixed bed chromatographic reactor for Fischer Tropsch synthesis

In this research, Fischer Tropsch synthesis (FTS) has been modeled in the fixed bed chromatographic reactor for the first time by applying a rather complex dispersed plug flow model for fluid phase and linear driving force (LDF) model for adsorbent. Model equations are dynamic, multi-component, non-linear and heterogeneous including reaction and adsorption simultaneously Complex kinetics fo...

full text

Kinetic Study of Fischer Tropsch Synthesis over co Precipitated Iron-Cerium Catalyst

The kinetic of Fischer-Tropsch synthesis over a co-precipitated Fe-Ce catalyst was investigated in a fixed bed micro reactor. Experimental conditions were varied as follow: reaction pressure 1-15bar, H¬¬¬2/CO feed ratio of 1-3 and space velocity of 3600-5400 h-1 at the temperature range of 270-310°C. 4 models according to the Langmuir-Hinshelwood-Hougen-Watson (LHHW) type rate equation were der...

full text

My Resources

Save resource for easier access later

Save to my library Already added to my library

{@ msg_add @}


Journal title

volume 3  issue 1

pages  78- 88

publication date 2015-03-01

By following a journal you will be notified via email when a new issue of this journal is published.

Hosted on Doprax cloud platform doprax.com

copyright © 2015-2023